Rhodium-Catalyzed Oxidative ortho-Acylation of Benzamides with Aldehydes: Direct Functionalization of the sp2 C–H Bond
Organic Letters2011Vol. 13(16), pp. 4390–4393
Citations Over TimeTop 1% of 2011 papers
Jihye Park, Eonjeong Park, Aejin Kim, Youngil Lee, Ki‐Whan Chi, Jong Hwan Kwak, Young Hoon Jung, In Su Kim
Abstract
A rhodium-catalyzed oxidative acylation of benzamides with aryl aldehydes via direct sp(2) C-H bond cleavage is described. In the presence of [Cp*RhCl(2)](2), AgSbF(6), and silver carbonate as an oxidant, N,N-diethyl benzamides can be effectively carbonylated to yield ortho-acyl benzamides.
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