Pd(0)-Catalyzed Iodoalkynation of Norbornene Scaffolds: The Remarkable Solvent Effect on Reaction Pathway
Organic Letters2011Vol. 13(19), pp. 5072–5075
Citations Over TimeTop 10% of 2011 papers
Abstract
A palladium-catalyzed iodoalkynation of norbornene has been realized with the use of alkynyl iodides 1, which is found to be strongly solvent-dependent. MeCN favors 1,7-iodoalkylation product 3 while CCl(4) leads to 1,2-iodoalkylation product 4.
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