Concise Formal Synthesis of (+)-Neopeltolide
Organic Letters2011Vol. 13(21), pp. 5916–5919
Citations Over TimeTop 10% of 2011 papers
Abstract
A concise formal synthesis of (+)-neopeltolide (1) has been accomplished. The synthesis demonstrated high atom efficiency employing only one step of functional group protection. Key steps involved iridium-catalyzed double asymmetric carbonyl allylation, palladium-catalyzed intramolecular alkoxycarbonylation, ruthenium-catalyzed olefin isomerization, and ring-closing metathesis.
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