Peroxide-Mediated Transition-Metal-Free Direct Amidation of Alcohols with Nitroarenes
Organic Letters2012Vol. 14(4), pp. 984–987
Citations Over TimeTop 10% of 2012 papers
Abstract
An unusual direct amidation of alcohols with nitroarenes mediated by peroxides has been discovered. The reaction tolerated a wide range of functionalities, and various aromatic amides were obtained in moderate to good yields in the absence of transition-metal catalyst. The peroxides and solvents had a significant impact on the reaction yield.
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