Isomerically Pure syn-Anthradithiophenes: Synthesis, Properties, and FET Performance
Organic Letters2012Vol. 14(14), pp. 3660–3663
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Dan Lehnherr, Andreas R. Waterloo, Katelyn P. Goetz, Marcia M. Payne, Frank Hampel, John E. Anthony, Oana D. Jurchescu, Rik R. Tykwinski
Abstract
The synthesis of isomerically pure syn-anthradithiophene derivatives (syn-ADTs) is described. X-ray crystallography is used to compare the solid-state arrangement of syn-ADT derivatives 2a,b to the analogous mixture of syn- and anti-ADTs. Single-crystal OFETs based on isomerically pure syn-ADTs 2a,b display device performance comparable to those based on a mixture of ADT isomers syn/anti-2a,b with mobilities as high as 1 cm(2)/(V s).
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