Selective and Effective Binding of Pillar[5,6]arenes toward Secondary Ammonium Salts with a Weakly Coordinating Counteranion
Organic Letters2012Vol. 14(16), pp. 4126–4129
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Abstract
The selective and effective binding of secondary ammoniums with a weakly coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (BArF) counteranion by per-ethylated pillar[5,6]arenes is reported. The construction of a first pillararene-based self-sorting system consisting of two wheels and two axles is also described.
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