Catalytic Radical Cation Salt Induced Csp3–H Functionalization of Glycine Derivatives: Synthesis of Substituted Quinolines
Organic Letters2012Vol. 14(15), pp. 4030–4033
Citations Over TimeTop 10% of 2012 papers
Abstract
A domino C(sp(3))-H functionalization of glycine derivatives was achieved under catalytic radical cation salt induced conditions, producing a series of quinolines. The proposed mechanism shows that a peroxyl radical cation, which is generated by the coupling between O(2) and TBPA(+•), might be involved to initiate the catalytic oxidation.
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