Kumada–Tamao–Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

Citations Over TimeTop 10% of 2012 papers

Abstract

The complex (IPr)Ni(allyl)Cl (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) catalyzes the cross-coupling reactions of heteroaromatic chlorides with aryl Grignard reagents. Catalyst loadings as low as 0.1 mol % have been used to afford the products in excellent yields. This nickel-based catalytic system also promotes the activation of the C(Ar)-O bond of anisoles in the Kumada-Tamao-Corriu reaction under fairly mild conditions.

Related Papers

• → Effect of Folin Reagent from Different Sources on Protease Determination(2013)1 cited
• → Fluorinated Organocopper Reagents(2011)1 cited
• STUDIES ON ANALYTICAL FUNCTIONAL GROUPS OF ORGANIC REAGENTS USED IN INORGANIC ANALYSIS——II.ON REAGENTS FOR ANTIMONOUS IONS(1956)
• Performance evaluation of stability of the total bile acid reagent with improved reagent bottles(2011)
• → ChemInform Abstract: Fluorinated Organocopper Reagents(2010)