Rh2(II)-Catalyzed Selective Aminomethylene Migration from Styryl Azides
Organic Letters2013Vol. 15(4), pp. 824–827
Citations Over TimeTop 10% of 2013 papers
Abstract
Rh(2)(II)-carboxylate complexes were discovered to promote the selective migration of aminomethylenes in β,β-disubstituted styryl azides to form 2,3-disubstituted indoles. Mechanistic data are also presented that suggest that the migration occurs stepwise before diffusion of the iminium ion.
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