Synthesis and Functionalization of [60]Fullerene-Fused Imidazolines

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Abstract

The silver carbonate promoted reaction of [60]fullerene with (Z)-N-arylbenzamidines afforded the unprecedented C60-fused imidazoline derivatives in high yields. Substrates with both electron-donating and -withdrawing groups on aromatic rings could be employed. In addition, the electrochemistry and further selective functionalization of the obtained C60-fused imidazolines were investigated.

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