Efficient Diels–Alder Addition of Cyclopentadiene to Lithium Ion Encapsulated [60]Fullerene
Organic Letters2013Vol. 15(17), pp. 4466–4469
Citations Over TimeTop 16% of 2013 papers
Abstract
Much higher reactivity of [Li(+)@C60]PF6(-) for Diels-Alder cycloaddition toward cyclopentadiene (CpH), in comparison with that of empty C60, was observed. The synthetic method, electrochemical and light absorption properties, and X-ray crystal structure of the product [Li(+)@C60(CpH)]PF6(-) are discussed.
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