P-Stereogenic PCP Pincer–Pd Complexes: Synthesis and Application in Asymmetric Addition of Diarylphosphines to Nitroalkenes
Organic Letters2013Vol. 15(21), pp. 5476–5479
Citations Over TimeTop 10% of 2013 papers
Abstract
Novel P-stereogenic PCP pincer-Pd complexes were designed and prepared in short steps from optically pure tert-butylmethylphosphine-borane. These optically active Pd-complexes were successfully applied in asymmetric addition of diarylphosphines to nitroalkenes with high yields and good enantioselectivity.
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