Radical Route for the Alkylation of Purine Nucleosides at C6 via Minisci Reaction
Organic Letters2013Vol. 16(2), pp. 444–447
Citations Over TimeTop 10% of 2013 papers
Abstract
A highly regioselective Minisci reaction with the decarboxylative alkylation of purine nucleosides under mild conditions was developed. With 5 mol % AgNO3 as a catalyst and (NH4)2S2O8 as an oxidant, a series of purine nucleosides including ribosyl, deoxyribosyl, arabinosyl purine nucleosides worked well with primary, secondary, and tertiary aliphatic carboxylic acids.
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