Copper-Catalyzed Intermolecular Aminoazidation of Alkenes
Organic Letters2014Vol. 16(6), pp. 1790–1793
Citations Over TimeTop 1% of 2014 papers
Abstract
Copper-catalyzed intermolecular aminoazidation of alkenes is described. This novel methodology provides an efficient approach to vicinal amino azides which can easily be transformed into other valuable amine derivatives. The commercially available N-fluorobenzenesulfonimide (NFSI) is used as a nitrogen-radical precursor and TMSN3 as the N3 source. Yields are moderate to excellent, and for internal alkenes aminoazidation occurs with excellent diastereoselectivity.
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