One-Pot Oxidation and Rearrangement of Propargylamines andin SituPyrazole Synthesis
Organic Letters2014Vol. 16(16), pp. 4146–4149
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Jinshan Chen, Roberta Properzi, Daniel P. Uccello, Jennifer A. Young, Russell G. Dushin, Jeremy T. Starr
Abstract
Reported here are procedures for a one-pot oxidation and rearrangement of propargylamines to synthesize enaminones, with supporting mechanistic studies. Also reported are the extended one-pot syntheses of pyrazoles, including celecoxib and various heterocyclic compounds.
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