Photoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of Alkenes
Organic Letters2014Vol. 16(16), pp. 4340–4343
Citations Over TimeTop 10% of 2014 papers
Abstract
We report herein a photoredox-catalyzed azidotrifluoromethylation of alkenes. Under the optimized conditions using [Ru(bpy)3(PF6)2] as the photocatalyst and Umemoto's reagent as the CF3 source, a wide range of substituted styrenes as well as various activated and nonactivated alkenes can readily be difunctionalized, affording β-trifluoromethylated azides or amines in good yields.
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