Iron-Catalyzed Alkylation of Alkenyl Grignard Reagents
Organic Letters2007Vol. 9(17), pp. 3253–3254
Citations Over TimeTop 1% of 2007 papers
Abstract
The first iron-catalyzed cross-coupling reaction between alkenyl Grignard reagents and n- or s-alkyl bromides is described. The reaction is stereoselective and takes place in the presence of 5 mol % of [Fe(acac)3/TMEDA/HMTA] (1:2:1) under very mild conditions (THF, 0 degrees C, 45 min).
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