Cu-Catalyzed Synthesis of Symmetric Group 6 (Fischer) Bis-carbene Complexes
Organic Letters2008Vol. 10(3), pp. 365–368
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Abstract
The efficient copper oxidative homocoupling (CuCl/TMEDA/O2) of alkynyl Fischer carbene complexes yields bis-carbene complexes having pi-tethers. The bimetallic complexes are exceptional templates to prepare diverse organic symmetric structures connected by pi-extended fragments.
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