A Highly Conjunctive β-Keto Phosphonate: Application to the Synthesis of Pyridine Alkaloids Xestamines C, E, and H
Organic Letters2007Vol. 10(2), pp. 253–256
Citations Over TimeTop 24% of 2007 papers
Abstract
The synthesis of a novel beta-keto gamma-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.
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