Hexafluoroisopropanol as a Unique Solvent for Stereoselective Iododesilylation of Vinylsilanes
Organic Letters2008Vol. 10(9), pp. 1727–1730
Citations Over TimeTop 10% of 2008 papers
Abstract
Stereoselective preparation of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of functionalized substrates.
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