Homoallyllic Nitrone Isomerization: Convenient Enantioselective Synthesis of Homoallylic Nitrones and Homoallylic Hydroxylamines
Organic Letters2008Vol. 10(13), pp. 2805–2807
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Abstract
An alpha-regioselective synthesis of homoallylic nitrones from aldehydes is reported on the basis of [3,3]-sigmatropic rearrangement. The products are obtained in up to 99% enantioselectivity and up to 80% yield under environmentally benign and mild reaction conditions.
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