Tetrathiophenalenyl Radical and its Disulfide-Bridged Dimer
Organic Letters2008Vol. 10(14), pp. 3121–3123
Citations Over TimeTop 10% of 2008 papers
Abstract
The presence of two disulfide groups in the tetrathiophenalenyl radical TTPLY leads to a highly delocalized spin distribution and the lowest cell potential ever observed for a monofunctional phenalenyl derivative. While the heteroatom substituents successfully block C-C bond formation, TTPLY nonetheless associates in the solid state to afford the hypervalent S-S-bonded dimer (TTPLY)2.
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