Instantaneous Deprotection of Tosylamides and Esters with SmI2/Amine/Water
Organic Letters2009Vol. 11(3), pp. 503–506
Citations Over TimeTop 10% of 2009 papers
Abstract
SmI(2)/amine/water mediates instantaneous cleavage of tosyl amides and tosyl esters. Highly hindered, sensitive and functionalized substrates were successfully deprotected in near quantitative yield.
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