Helical Organization in Foldable Aromatic Oligoamides by a Continuous Hydrogen-Bonding Network
Organic Letters2009Vol. 11(6), pp. 1201–1204
Citations Over TimeTop 10% of 2009 papers
Abstract
Introduction of a continuous internal hydrogen-bonding network suppressed the conformational flexibility of a series of oligoaromatic foldamers with a lengthened backbone. The helical ordering over up to six aromatic repeating units was established in solution by a 2D NOESY study and in the solid state by an X-ray diffraction method. Computational molecular modeling further corroborates the experimentally observed helical propagation in this class of foldable molecular strands.
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