Imidazolium-Functionalized BINOL as a Multifunctional Receptor for Chromogenic and Chiral Anion Recognition
Organic Letters2009Vol. 11(3), pp. 669–672
Citations Over TimeTop 1% of 2009 papers
Abstract
A novel imidazolium-functionalized BINOL fluorescent receptor R-1 was developed as a multifunctional receptor for both chromogenic and chiral anion recognition. The different fluorescent responses and color changes of R-1 could be applied to the detection of fluoride and acetate ions by the naked eye. Furthermore, the chiral recognition of the two enantiomers of alpha-amino carboxylates was also studied, and R-1 displayed a remarkable binding ability for the t-Boc alanine anion with an interesting enantioselectivity (K(L)/K(D) = 4.5).
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