Gold(III) Chloride Catalyzed Synthesis of 1-Cyanoisoindoles
Organic Letters2009Vol. 11(21), pp. 5018–5021
Citations Over TimeTop 10% of 2009 papers
Abstract
A two-step synthesis of 1-cyanoisoindoles starting from ethynylbenzaldehyde is presented. The key step is a mild, high-yielding, gold-catalyzed rearrangement of N-allylic aminonitriles.
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