Some Allylic Substituent Effects in Ring-Closing Metathesis Reactions: Allylic Alcohol Activation
Organic Letters1999Vol. 1(7), pp. 1123–1125
Citations Over TimeTop 10% of 1999 papers
Abstract
[formula: see text] Dienes 2a-e were used to study allylic substituent effects in the ring-closing metathesis reaction (RCM). Both the steric and electronic character of the allylic substituents were found to influence alkene reactivities. Free allylic hydroxyl groups exert a large activating effect on the RCM reaction rates.
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