Hydrolytic Reactivity of a Samarium(II) Organometallic Complex: Synthesis and Structure of a Hexametallic Organosamarium Oxide Hydroxide, [(C5Me5)Sm]6O9H6
Organometallics2001Vol. 20(13), pp. 2936–2937
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Abstract
Controlled hydrolysis of the divalent organosamarium complex (C5Me5)2Sm(THF)2 in THF forms [(C5Me5)Sm]6O9H6, 1, which has a solid-state structure consisting of a distorted octahedral array of six [(C5Me5)Sm]2+ units connected by eight triply bridging oxygens and a central oxygen.
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