Construction of Supported Organometallics Using Cycloplatinated Arylamine Ligands
Organometallics2001Vol. 21(2), pp. 264–271
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Michel D. Meijer, Arjan W. Kleij, B. Scott Williams, D.D. Ellis, Martin Lutz, Anthony L. Spek, G.P.M. Van Klink, Gerard van Koten
Abstract
The preparation of ortho-chelating aminoaryl ligands ([C6H3(CH2NMe2)-2-R-4]-, abbreviated as C,N) containing a pendant hydroxymethyl group is described. These ligands have been cycloplatinated with cis-PtCl2(DMSO)2, yielding the corresponding C,N-platinum(II) complexes. The pendant hydroxymethyl substituent is a versatile group for attachment of the organometallic moiety to macromolecules, which has been demonstrated by attaching the C,N-platinum complexes to a dendritic wedge and to C60.
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