The First Structurally Characterized Example of a η5-Coordinate Mesitylato Palladium Complex
Organometallics2002Vol. 21(11), pp. 2340–2342
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Abstract
The red complex [(COD)Pd(OMes)](SbF6) (OMes = 2,4,6-trimethylphenolate = mesitylate) was prepared and structurally characterized. The molecular structure reveals that the palladium atom coordinates η5 to the aryl π system and not to the negatively charged oxygen atom on the mesitylate ligand.
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