Cyclic Di- and Mixed-Valent Ytterbium Complexes Supported by Dipyrrolide Ligands
Organometallics2002Vol. 21(6), pp. 1240–1246
Citations Over TimeTop 10% of 2002 papers
Abstract
The reaction of YbI2(THF)2 with diphenyldipyrrolylmethanide leads to a complex reaction from which an octameric divalent Yb macrocyclic complex, [diphenyldipyrromethanediyl-Yb]8, was obtained as a major product. A tetrameric cyclic Yb(II)-oxo complex, [(diphenyldipyrrolylmethanediyl)Yb]4[(K(THF)3]2(μ-O)·2(THF), arising from solvent deoxygenation and a monomeric Yb(III) complex, Yb(diphenyldipyrrolylmethanediyl)3[K(THF)]3, were also isolated as byproducts of a complex reaction.
Related Papers
- → Reductive Deoxygenation of Alcohols: Catalytic Methods Beyond Barton–McCombie Deoxygenation(2013)118 cited
- → 1,2-Deoxygenation of vic-Dihydroxyindenoimidazoles: Optimization of a Novel Deoxygenation Reagent(2004)11 cited
- → Decomposition of glucose with in situ deoxygenation in a low H2 pressure environment – Part I: Monometallic catalysts(2018)7 cited
- → Study of new facile deoxygenation methods in cyclodextrin induced room temperature phosphorescence(1997)22 cited
- → Deoxygenation of Alcohols and CC Coupling Reactions(1998)