Iminophosphine Palladium Complexes in Catalytic Stille Coupling Reactions: From Monomers to Dendrimers
Organometallics2002Vol. 21(22), pp. 4680–4687
Citations Over TimeTop 10% of 2002 papers
Marek Koprowski, Rosa Marı́a Sebastián, Valérie Maraval, Maria Zabłocka, Victorio Cadierno, B. Donnadieu, Alain Igau, Anne‐Marie Caminade, Jean‐Pierre Majoral
Abstract
Palladium complexes of a variety of β- and γ-iminophosphines have been prepared and characterized by X-ray diffraction studies. Their properties as catalyst for three different Stille coupling reactions have been investigated and compared to catalytic performances of a phosphorus-containing dendrimer incorporating analogous γ-iminophosphine palladium complexes on the surface.
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