Novel Metallacycle Complexes from Bis(oxazolinyl)pyridine−Rhodium(I) Species and Diynes
Organometallics2002Vol. 21(13), pp. 2572–2574
Citations Over TimeTop 19% of 2002 papers
Abstract
The reaction of [Rh(coe)2Cl]2 (coe = cis-cyclooctene), bis(oxazolinyl)pyridine (pybox), and diynes (O(CH2C⋮CCO2Me)2 and PhC⋮CCH2OCH2C⋮CCO2Me) gave new types of metallacycle complexes, which were analyzed by X-ray crystallography and showed catalytic activity for cycloaddition of diynes and several alkynes.
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