Silver Complexes of a Novel Tripodal N-Heterocyclic Carbene Ligand: Evidence for Significant Metal−Carbene π-Interaction
Organometallics2003Vol. 22(4), pp. 612–614
Citations Over TimeTop 10% of 2003 papers
Abstract
A novel N-heterocyclic tridentate polycarbene ligand has been synthesized and stabilized as its corresponding silver complex. An electronic structure investigation reveals significant π-bonding interactions within the Ag−carbene unit of the [(TIMEMe)2Ag3]3+ cation.
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