Synthesis, Structure, and Reductive Elimination Reactions of the First (σ-Aryl)palladium Complex Stabilized by IPr N-Heterocyclic Carbene
Organometallics2003Vol. 22(8), pp. 1591–1593
Citations Over TimeTop 10% of 2003 papers
Abstract
The first (σ-aryl)palladium complex stabilized with one IPr N-heterocyclic carbene and one PPh3 ligand has been synthesized via a novel method, structurally characterized, and found to undergo remarkably facile C−C reductive elimination of the 2-phenylimidazolium cation via phosphine predissociation.
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