A Ruthenium Olefin Metathesis Catalyst with a Four-Membered N-Heterocyclic Carbene Ligand
Organometallics2004Vol. 24(3), pp. 338–340
Citations Over TimeTop 10% of 2004 papers
Abstract
The first ruthenium olefin metathesis catalyst bearing a four-membered N-heterocyclic carbene (5) was synthesized and characterized by NMR spectroscopy and X-ray crystallography. The synthesis of a (carbene)carbonylrhodium complex (6) was also reported, allowing the study of the electronic properties of this new carbene ligand. The complex 5 was screened toward different olefin metathesis reactions, and it showed a slow reactivity.
Related Papers
- → Mechanochemical Ruthenium-Catalyzed Olefin Metathesis(2015)174 cited
- → A Thermally Switchable Latent Ruthenium Olefin Metathesis Catalyst(2008)150 cited
- → Olefin cross metathesis and ring-closing metathesis in polymer chemistry(2017)77 cited
- → Phosphite ligands in Ru-based olefin metathesis catalysts(2015)18 cited
- Ruthenium-based olefin metathesis catalysts bearing new N-heterocyclic carbenes(2005)