Platinum-Catalyzed Intermolecular Hydroamination of Unactivated Olefins with Carboxamides
Organometallics2004Vol. 23(8), pp. 1649–1651
Citations Over TimeTop 10% of 2004 papers
Abstract
Reaction of benzamide with a catalytic 1:2 mixture of [PtCl2(H2CCH2)]2 (2.5 mol %) and PPh3 in dioxane at 120 °C for 24 h led to isolation of N-ethylbenzamide in 97% yield. A range of primary, acyclic aryl and alkyl carboxamides and secondary cyclic carboxamides and carbamates also underwent platinum-catalyzed addition to ethylene and propylene.
Related Papers
- → Gold‐Catalyzed Hydroamination of C–C Multiple Bonds(2006)501 cited
- → TiCl4-Catalyzed Intermolecular Hydroamination Reactions(2003)92 cited
- → Rh(i) and Ir(i) catalysed intermolecular hydroamination with substituted hydrazines(2008)35 cited
- → Synthesis of 7-Aza-5-deazapurine Analogues via Copper(I)-Catalyzed Hydroamination of Alkynes and 1-Iodoalkynes(2010)30 cited
- → HOTf-catalyzed intermolecular hydroamination reactions of alkenes and alkynes with anilines(2015)13 cited