Anodic Electrochemistry of Ferrocenylphosphine and Ruthenocenylphosphine Chalcogenide Complexes and Lewis Acid Adducts
Organometallics2005Vol. 24(10), pp. 2447–2451
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Abstract
The anodic electrochemistry of a series of bidentate phosphine chalcogenides and bidentate phosphine Lewis acid adducts, both with a metallocene backbone, was examined in dichloromethane containing [NBu4][PF6]. Oxidation of the ferrocene compounds dppfE2 and dippfE2 (E = O, S, BH3, CH3+) was reversible on the cyclic voltammetric (CV) time scale, while the oxidation of the dpprE2 compounds (E = O, S, BH3) was irreversible; however, the oxidation of dppfSe2, dippfSe2, and dpprSe2 displayed an irreversible wave and the reduction of a follow-up product.
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