Reaction of Diphenylgermane with (Ph3P)2Pt(η2-C2H4): Generation of Mono- and Dinuclear Complexes Containing Pt−Ge Bonds. X-ray Crystal Structure Determination of [(Ph3P)Pt(μ-η2-H-GePh2)]2
Organometallics2005Vol. 24(17), pp. 4113–4115
Citations Over TimeTop 15% of 2005 papers
Abstract
The reaction of diphenylgermane (Ph2GeH2) with (Ph3P)2Pt(η2-C2H4) provided both mononuclear (Ph3P)2Pt(H)(GePh2H) and dinuclear [(Ph3P)Pt(μ-η2-H-GePh2)]2 complexes. The structure of the dinuclear complex was determined by X-ray crystallography. The dinuclear complex could also be obtained from an unusual exchange reaction involving the unsymmetrical dinuclear complex [(Ph3P)2(H)Pt(μ-SiR2)(μ-η2-H-SiR2)Pt(PPh3)] (SiR2 = SiC20H24) with Ph2GeH2.
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