Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways
Organometallics2007Vol. 26(4), pp. 1108–1111
Citations Over TimeTop 10% of 2007 papers
David S. McGuinness, Matthew J. Overett, Robert P. Tooze, Kevin Blann, John T. Dixon, Alexandra M. Z. Slawin
Abstract
Chromium-based ethylene tri- and tetramerization catalysts have been evaluated with a combination of trialkylaluminium and borate cocatalyst activation. A remarkable effect on activity and selectivity has been observed and studied, and a cocatalyst-induced degradation pathway has been identified. 2007 American Chemical Society.
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