Calcium-Catalyzed Intermolecular Hydrophosphination
Organometallics2007Vol. 26(12), pp. 2953–2956
Citations Over TimeTop 10% of 2007 papers
Mark R. Crimmin, Anthony G. M. Barrett, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou
Abstract
The β-diketiminato complex [{HC(C(Me)2N-2,6-iPr2C6H3)2}Ca{N(SiMe3)2}(THF)] effects intermolecular hydrophosphination of a range of alkenes and alkynes. In behavior reminiscent of lanthanocene(III) catalysis, a more electrophilic alkene is polymerized to phosphine-terminated macromolecules.
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