A Versatile Cuprous Synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
Organometallics2010Vol. 29(17), pp. 3966–3972
Citations Over TimeTop 10% of 2010 papers
Abstract
The novel 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (hydroxy) copper ([Cu(IPr)(OH)]) exhibits a versatile capacity to activate numerous X−H bonds including all major hybridizations of C−H (i.e., sp, sp2, sp3), N−H, P−H, O−H, S−H, and one example of M−H (M = Mo) bonds. This reactivity also includes the cleavage of the Si−N and Si−C bonds to form unprecedented Cu-centered complexes.
Related Papers
- → SF5-Synthons: Pathways to Organic Derivatives of SF6(2005)31 cited
- → Cu(II)-Catalyzed [3 + 1 + 1 + 1] Cyclization of 1,3-Diketones and 2-Naphthols Using N,N-Dimethylethanolamine as a Dual Carbon Synthon for the Synthesis of 2H-Chromenes(2023)11 cited
- → Supramolecular Synthons: Will Giant Rigid Superspheres Do?(2016)16 cited
- → Mathematical Model of Synthon Reactions(1989)1 cited
- → ChemInform Abstract: Ethynylglycine Synthon, a Useful Precursor for the Synthesis of Biologically Active Compounds: an Update ‐ Part I: Preparations of Ethynylglycine Synthon(2015)