Aqueous Organometallic Chemistry of mer-Ir(H)2(PMe3)3X Complexes
Organometallics2012Vol. 31(10), pp. 3920–3929
Citations Over TimeTop 24% of 2012 papers
Abstract
A series of Ir(H)2(PMe3)3X compounds where X = various anionic ligands has been synthesized. The most studied of this group with X = Cl has been characterized fully, including by X-ray crystallography. For X = Cl, PhCO2–, dissolution in water results in the establishment of the equilibrium Ir(H)2(PMe3)3X + H2O ⇌ [Ir(H)2(PMe3)3(H2O)]+X–, which is responsible for the reaction of these compounds with unsaturated organic compounds. Reactions between the dihydrides and alkynes in water as well as the thermodynamics of the aqueous equilibrium are discussed.
Related Papers
- → Supported Catalysts Obtained by Interaction of Organometallic Compounds of Transition Elements with Oxide Supports(1976)226 cited
- Organometallic Chemistry: A Unified Approach(1991)
- → Analytical Applications of Vibrational Spectroscopy in Bioorganometallic Chemistry(1997)1 cited
- → What Are Organometallic Compounds?(2023)
- Functional materials, environmental and biological applications(2007)