Synthesis and Structure of Cationic Phosphine Gold(I) Enol Ether Complexes
Organometallics2012Vol. 31(21), pp. 7332–7335
Citations Over TimeTop 10% of 2012 papers
Abstract
Cationic {[(t-Bu)2(o-biphenyl)P]Au(enol ether)}+SbF6– and {[(t-Bu)3P]Au(enol ether)}+SbF6– complexes were isolated and characterized by NMR spectroscopy and X-ray crystallography. For three of the four complexes characterized in the solid state, gold coordinates to the electron-rich bond in a η1 fashion, while a 2,3-dihydrofuran complex displays η2 coordination.
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