[Pd(IPr*OMe)(acac)Cl]: Tuning the N-Heterocyclic Carbene in Catalytic C–N Bond Formation
Organometallics2012Vol. 32(1), pp. 330–339
Citations Over TimeTop 10% of 2012 papers
Abstract
A new N-heterocyclic ligand IPr*OMe [N,N′-bis(2,6-bis(diphenylmethyl)-4-methoxyphenyl)imidazol-2-ylidene] has been synthesized and compared with its earlier methyl-substituted congener IPr* [N,N′-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene]. IPr*OMe was successfully bound to palladium, and the catalytic activity of the resulting complex [Pd(IPr*OMe)(acac)Cl] was investigated in Buchwald–Hartwig arylamination. Catalytic activity was compared to that of [Pd(IPr*)(acac)Cl].
Related Papers
- → A Stable Four-Membered N-Heterocyclic Carbene(2004)139 cited
- → Stabilization of the Elusive 9‐Carbene‐9‐Borafluorene Monoanion(2021)12 cited
- → Preparation of organo palladium sols from palladium complexes in various alcohols(1994)32 cited
- → Preparation of new hydridoplatinum(II) carbene derivatives from hydridotrifluoromethyl complexes(1985)27 cited
- → Carbene Complexes — Complexes with MC Double Bonds(2021)