Iron-Catalyzed Borylation of Alkyl, Allyl, and Aryl Halides: Isolation of an Iron(I) Boryl Complex
Organometallics2014Vol. 33(21), pp. 5940–5943
Citations Over TimeTop 10% of 2014 papers
Robin B. Bedford, Peter B. Brenner, Emma Carter, Timothy Gallagher, Damien M. Murphy, Dominic R. Pye
Abstract
Activation of B2pin2 with tBuLi facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B2pin2(tBu)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)2] (2).
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