Insertion of a N-Heterocyclic Carbene (NHC) into a Platinum−Olefin Bond
Organometallics2007Vol. 26(14), pp. 3286–3288
Citations Over TimeTop 10% of 2007 papers
Abstract
The insertion of a N-heterocyclic carbene (NHC) into a coordinated olefin moiety is observed for a Pt-based system. Important intermediates along the reaction pathway have been isolated and fully characterized. Computational work supports a proposed mechanistic pathway involving external attack at the olefin by a NHC ligand rather than an intramolecular migratory insertion route.
Related Papers
- → Formal Carbene Insertion into C–C Bond: Rh(I)-Catalyzed Reaction of Benzocyclobutenols with Diazoesters(2014)201 cited
- → Aminopalladation‐Triggered Carbene Insertion Reaction: Synthesis of 2‐(1H‐Indol‐3‐yl)acetates(2015)23 cited
- → Acyl–Carbene and Methyl–Carbene Coupling via Migratory Insertion in Palladium Complexes(2012)21 cited
- → Studies of intramolecular alkylidene carbene reactions; an approach to heterocyclic nucleoside bases(2003)15 cited
- → Dicyclometalated Mononuclear Bis(carbene)platinum(IV) Complexes(1998)18 cited