Ln[N(SiMe3)2]3/RNH2 Catalyzed Monoaddition of Terminal Alkynes to Nitriles: A Novel and Concise Access to the Synthesis of Ynones
Organometallics2008Vol. 27(2), pp. 301–303
Citations Over TimeTop 10% of 2008 papers
Abstract
A mild and highly selective Ln[N(SiMe3)2]3/n-BuNH2 catalyzed addition of terminal alkynes to nitriles has been established, revealing a novel reactivity pattern of alkynes with nitriles and providing a new, economical, and mild method for the synthesis of conjugated ynones.
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