Heavier Group 2 Element Catalyzed Hydrophosphination of Carbodiimides
Organometallics2008Vol. 27(4), pp. 497–499
Citations Over TimeTop 10% of 2008 papers
Mark R. Crimmin, Anthony G. M. Barrett, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou
Abstract
Amides of the heavier group 2 elements Ca, Sr, and Ba are effective precatalysts for the atom-efficient addition of phosphine P−H bonds to carbodiimides. A number of intermediates within the catalytic cycle have been identified by in situ NMR methods and by stoichiometric synthesis.
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