Thiazolyl Phosphine Ligands for Copper-Catalyzed Arylation and Vinylation of Nucleophiles in Organic and Aqueous Media
Organometallics2008Vol. 27(21), pp. 5733–5736
Citations Over TimeTop 18% of 2008 papers
Gennady V. Oshovsky, Armelle Ouali, Ning Xia, Maria Zabłocka, Renè T. Boeré, Carine Duhayon, Marc Taillefer, Jean‐Pierre Majoral
Abstract
A straightforward and efficient synthetic route to thiazolyl phosphines is reported. Moreover, the first application of these molecules in catalysis is described. These phosphines are excellent ligands in the copper-catalyzed arylation and vinylation of nucleophiles. The reactions could be performed in acetonitrile and various mixed aqueous/organic solvents and even in pure water in the presence of a phase transfer catalyst. In each case, coupling products are obtained with high yields at very mild temperatures.
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